Comparison between one-time imaging printing plate and repeated imaging printing plate process III
4 convertible polymer
the term switchable polymer appears quite frequently when referring to repeatable imaging printing plate. Here, the term "transformable" refers to that when a material is used as a printing plate, its surface characteristics can be changed from one state to another, which is the basic characteristics that repeatable imaging materials should have. Based on the surface characteristics of the printing plate used in the offset printing process, "transformable" means that the basic state of the surface of the printing plate material is hydrophilic, but it can be changed to another state by specific process means. Fig. 3 explains the principle of reverse transformation of surface characteristics of materials with 4 times of the maximum working pressure in the burst pressure experiment
in the process of changing the surface properties of materials, the physical properties of the interface can be changed by some physical and chemical means, such as changing from the surface with oleophobic characteristics to the surface with oleophobic characteristics. The surface with this characteristic is called inkfriendly surface. This state is permanently stored in the material throughout the printing cycle, so stable printing quality can be produced, and the printed image has no visual changes. If the image on the printing plate can be erased after printing, the printing plate can be restored to its original state, and the erasure process can also be achieved through physical and chemical effects. At this time, the physical properties of the interface of the material change again, for example, from the ink friendly state to the hydrophilic initial state, which means that the whole surface can be moistened by the fountain solution. Therefore, the plate material that can be imaged repeatedly should have reversible transformation characteristics. This surface characteristic is called transformation characteristics. In addition to polymers, other materials may also have such characteristics, so the term "convertible polymer" may be misleading
the basic properties of materials will determine their erasable, repeatable imaging and information recording (storage) characteristics, as well as the service life of imaging results and the number of times of erasable and imaging in a production cycle
it should be pointed out that the basic properties of printing plate materials must match the imaging components and process performance used in the imaging system, that is, the physical and chemical processes generated in the printing plate during imaging can be reflected by different physical effects. Therefore, plate materials with different properties can be imaged through different processes, such as thermal imaging, electrophotographic imaging or ion imaging. The same material may also produce a variety of process uses, such as using specific inks to image on printing plates with thermal sublimation technology, or imaging through inkjet systems and image curing processes
multiple imaging of a printing plate can be achieved by the application and cancellation of some surface characteristics of the material, or the deletion and rewriting of the stored contents of the printing plate can be achieved without the separate application of the interface physical and chemical effects of the material
5 surface material of reproducible imaging printing plate
for researchers of reproducible imaging printing plate materials, their most concerned problem is the reverse change of material state. As long as the basic properties of the material show the ability of reverse change, we can try to change its surface properties. An example is the content of oxygen in metal oxides (such as titanates). When the oxygen content in the metal oxide is different, the material has different writing characteristics. When the oxygen content of the surface material is in a normal state, its basic characteristics are hydrophilic. Laser radiation can be used to reduce the low oxygen content, so that the surface characteristics of the material can be changed into lipophilic. When it is necessary to restore it to its initial state, the material can be heat treated to restore the oxygen content of the surface material. The price increase of battery grade lithium carbonate between piers and bridges by 7% is soft to the normal level, so it becomes hydrophilic again
similarly, through appropriate radiation, it is possible to restore photocatalytic materials such as zinc oxide or titanate to a hydrophilic (ink repellent) state
the interface physical phenomenon of polymer is contrary to the material properties mentioned above. It has a functional side chain structure, such as fluoropolymer. Some of these substances are related to the damage of PTF to the experimental machine. We have a lot of technical data for you to learn about e (called Teflon), which can be used as offset repeated imaging surface. For these materials, the term "transformable polymer" is appropriate. (author: yaohaigen)
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